Handbook of Layered Materials

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Focusing on layered compounds at the core of materials intercalation chemistry, this reference comprehensively explores clays and other classes of materials exhibiting the ability to pillar, or establish permanent intracrystalline porosity within layers. It offers an authoritative presentation of their fundamental properties as well as summaries of

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Contents

Introduction Clay Structure Surface Acidity and Catalysis
1
Molecular Modeling of Clay Mineral Structure and Surface Chemistry
39
ClayOrganic Interactions Organoclay Complexes and PolymerClay Nanocomposites
91
Sorption of Nitroaromatic Compounds on Clay Surfaces
155
Photoprocesses in ClayOrganic Complexes
191
Pillared Clays and Porous Clay Heterostructures
261
Layered aZirconium Phosphates and Phosphonates
313
Layered Double Hydroxides LDHs
373
Layered Manganese Oxides Synthesis Properties and Applications
475
Layered Metal Chalcogenides
509
Alkali Silicates and Crystalline Silicic Acids
541
Index
631
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Page 1 - Government retains for itself, and others acting on its behalf, a paid-up, nonexclusive, irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly and display publicly, by or on behalf of the Government.
Page 279 - In recent years a number of investigations have been carried out to study adsorption in pillared clays, almost all of which are experimental in nature.
Page 308 - Zeolite Synthesis," ACS Symp. Ser. 398 (1989) 11. [78] JC Jansen in [14, p. 77]. [79] EJP Feijen, JA Martens, PA Jacobs in J. Weitkamp, HG Karge, H. Pfeifer, W. Holderich (eds.): "Zeolites and Related Microporous Materials: State of the Art 1994,
Page 36 - KSW Sing, DH Everett, RAW Haul, L. Moscou, RA Pierotti, J. Rouquerol and T. Siemieniewska, Pure Appl. Chem., 57 (1985) 603.
Page 34 - Laboratory was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences, under DOE Contract No.
Page 1 - The term clay refers to a naturally occurring material composed primarily of fine-grained minerals, which is generally plastic at appropriate water contents and will harden when dried or fired.
Page 252 - A. Juris, V Balzani, F. Barigelletti, S. Campagna, P. Belser, A. Von Zelewsky, Coord Chem. Rev. 84, 85 (1988).
Page 266 - Adjacent layers are stacked in such a way that the potassium ion is equidistant from 12 oxygens, 6 of each layer (Fig.
Page 25 - Walling 34 suggests a similar definition for the acid strength as the ability of the surface to convert an adsorbed neutral base to its conjugate acid where Ho =-log(aAfB/ fAfi) (2) Where now, aA is the activity of the Lewis acid or electron acceptor.
Page 150 - A. Usuki, , Y. Kojima, M. Kawasumi, A. Okada, Y. Fukushima, T. Kurauchi, and O. Kamigaito, J. Mater. Res.

About the author (2004)

Scott M. Auerbach (Author) , Kathleen A. Carrado (Author) , Prabir K. Dutta (Author)

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