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"Ringelmann chart” means the chart published and described in the U.S. Bureau of Mines Information Circular 8333.

"Source” means any property, real or personal, which emits or may emit any air pollutant.

“Stack" means any chimney, flue, conduit, or duct arranged to conduct emissions to the ambient air.

“Standard conditions" mean & dry gas temperature of 70° Fahrenheit and a gas pressure of 14.7 pounds per square inch absolute.

"Submerged All pipe" means any all pipe the discharge opening of which is entirely submerged when the liquid level is 6 inches (15 cm.) above the bottom of the tank; or when applied to a tank which is loaded from the side, means any fill pipe the discharge opening of which is entirely submerged when the liquid level is 18 inches (45 cm.) above the bottom of the tank.

"Volatile organic compounds" means any compound containing carbon and hydrogen or containing carbon and hydrogen in combination with any other element which has a vapor pressure of 1.5 pounds per square inch absolute (77.6 mm. Hg) or greater under actual storage conditions.

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APPENDIX B-EXAMPLES OF EMISSION LIMITA

TIONS ATTAINABLE WITH REASONABLY AVAILABLE TECHNOLOGY

This appendix sets forth emission limitations which, in the Administrator's Judgment, are attainable through the application of reasonable available emission control technology. The statements presented herein are not intended, and should not be construed, to require or encourage State agencies to adopt such emission limitations without consideration of (1) the necessity of imposing such emission limitations in order to attain and maintain a national standard, (2) the social and economic impact of such emission limitations, and (3) alternative means of providing for attainment and maintenance of a national standard. Fallure of a State agency to adopt any or all of the emission limitations set forth herein will not be grounds for rejecting a State implementation plan is that implementation plan provides for attainment and maintenance of the National Ambient Air Quality Standards within the time prescribed by the Clean Air Act. Nor will State adoption of any or all of these emission limitations be grounds for approval of an implementation plan that does not provide for timely attainment and maintenance of the national standards. In preparing implementation plans, State agencies should tallor their control strategies to deal with the particular problems and meet the particular needs of their own States.

1.0 DEFINITIONS "Alr pollutant" means dust, fumes, mist, smoke, other particulate matter, vapor, gas, odorous substances, or any combination thereof.

"Efuent water separator" means any tank, box, sump, or other container in which any volatile organic compound floating on or entrained or contained in water entering such tank, box, sump, or other container is physically separated and removed from such water prior to outfall, drainage, or recovery of such water.

"Emission" means the act of releasing or discharging air pollutants into the ambient air from any source.

"Fuel-burning equipment” means any furnace, boiler, apparatus, stack, and all appurtenances thereto, used in the process of burning fuel for the primary purpose of producing heat or power by Indirect heat transfer.

“Fugitive dust" means solid, airborne particulate matter emitted from any source other than through a stack,

"Opacity" means & state which renders material partially or wholly impervious to rays of light and causes obstruction of an observer's view.

"Particulate matter" means any material, except water in uncombined form, that is or has been airborne and exists as a liquid or a solid at standard conditions.

2.1 Visible emissions. The emission of visible air pollutants can be limited to a shade or density equal to but not darker than that designated as No. 1 on the Ringelmann chart or 20 percent opacity except for brief periods during such operations as soot blowing and startup. This limitation would generally eliminate visible pollutant emis. sions from stationary sources.

The emission of visible alr pollutants from gasoline-powered motor vehicles can be eliminated except for periods not exceeding 5 consecutive seconds. The emission of visible air pollutants from diesel-powered motor vehicles can be limited to a shade or density equal to but not darker than that designated as No. 1 on the Ringelmann chart or 20 percent opacity except for periods not exceeding 5 consecutive seconds.

2.2 Fugitive dust. Reasonable precautions can be taken to prevent particulate matter from becoming airborne. Some of these reasonable precautions include the following:

(a) Use, where possible, of water or chemicals for control of dust in the demolition of existing buildings or structures, construction operations, the grading of roads or the clearing of land;

(b) Application of asphalt, oll, water, or suitable chemicals on dirt roads, materials stockplles, and other surfaces which can give rise to airborne dusts;

(c) Installation and use of hoods, fans, and fabric Alters to enclose and vent the handling of dusty materials. Adequate con

talament methods can be employed during sandblasting or other similar operations;

(d) Covering, at all times when in motion, open bodied trucks, transporting materials likely to give rise to airborne dusts;

(e) Conduct of agricultural practices such as tulling of land, application of fertilizers, etc., in such manner as to prevent dust from becoming airborne;

(1) The paving of roadways and their maintenance in a clean condition;

(8) The prompt removal of earth or other material from paved streets onto which earth or other material has been transported by trucking or earth moving equipment, erosion by water, or other means.

2.3 Incineration. The emission of particulate matter from any incinerator can be lim. Ited to 0.20 pound per 100 pounds (2 gm/kg.) of refuse charged. This emission limitation is based on the source test method for stationary sources of particulate emissions which will be published by the Administrator. This method includes both & dry filter and wet impingers and represents particulate matter of 70° F. and 1.0 atmosphere pressure.

2.4 Fuel burning equipment. The emisson of particulate matter from fuel burning equipment burning solid fuel can be limited to 0.30 pound per million B.t.u. (0.54 gm/106 gm-cal) of heat input. This emission limitation is based on the source test method for stationary sources of particulate emissions which will be published by the Administrator. This method includes both a dry filter and wet impingers and represents particulate matter of 70' F. and 1.0 atmosphere pressure.

2.5 Process industries-general. The emisston of particulate matter for any process source can be limited in a manner such as in table I. Process weight per hour means the total weight of all materials introduced into any specific process that may cause any omission of particulate matter. Solid fuels charged are considered as part of the process weight, but liquid and gaseous fuels and combustion alr are not. For a cyclical or batch operation, the process weight per hour 18 derived by dividing the total process weight by the number of hours in one complete operation from the beginning of any given process to the completion thereof, excluding any time during which the equipment 18 idle. For a continuous operation, the process weight per hour is derived by dividing the process weight for a typical period of time.

TABLE I
Process

Emission
weight rate

rate (lbs./hr.)

(lbs./hr.) 60

0.36 100

0.55 500

1.53 1,000

2. 25 5,000

6. 34 10,000

9.73 20,000

14. 99 60,000

29.60

TABLE 1-Continued
Process

Emission
weight rate

rate (lbs./hr.)

(lbs./hr.) 80,000

31. 19 120,000

33. 28 160,000

34. 85 200,000

36. 11 400,000

40. 35 1,000,000

46. 72 Interpolation of the data in table I for the process weight rates up to 60,000 lbs./hr. shall be accomplished by the use of the equation:

E=3.59 po.es P$30 tons/hr. and interpolation and extrapolation of the data for process weight rates in excess of 60,000 lbs./hr. shall be accomplished by use of the equation:

E=17.31 po.za PS30 tons/hr. Where: E=Emissions in pounds per hour.

P=Process weight rate in tons per

hour. Application of mass emission limitations on the basis of all similar units at a plant is recommended in order to avoid unequal application of this type of limitation to plants with the same total emission potential but different size units. 3.0 CONTROL OF SULFUR COMPOUND

EMISSIONS 3.1 Fuel combustion. It is not possible to make nationally applicable generalizations about attainable degrees of control of sulfur oxides emissions from combustion sources. Avallability of low-sulfur fuels varies from one area to another. In some areas, severe restrictions on the sulfur content of fuels could have a significant impact on fuel-supply patterns; accordingly, where such restrictions are necessary for attainment of national amblent air quality standards, adoption of phased schedules a sulfur-in-fuel limitations is recommended. Stack gas cleaning is feasible at large industrial combustion sources and steam electric power plants. Technology has been demonstrated which will allow 70 percent removal of sulfur oxides from combustion gases of most existing fuel burning units.

Alternative means of meeting requirements for the control of sulfur oxides emissions from fuel combustion sources include: Use of natural gas, distillate oul, low-sulfur coal, and low-sulfur residual oil; desulfurlzation of oil or coal; stack gas desulfurization; and restricted use, shutdown, or relocation of large existing sources.

It is technically feasible to produce or desulfurize fuels to meet the following specifications: Distillate oll—0.1 percent sulfur (though it should be noted that distillato oll containing less than 0.2 percent sulfur is not generally available at this time); residual oil—0.3 percent sulfur; bituminous coal0.7 percent sulfur. Availability of significant quantities of such low-sulfur fuels in any region where they do not naturally occur or have not been imported from other domestic or foreign sources will require planning for the timely development of new sources of such fuels. Because residual oil generally is obtained from overseas sources,

its use ordinarily is restricted to areas accessible to waterborne transportation. There are limited tonnages of 0.7 percent sulfur coal produced at the present time, primarily in the western United States; large reserves of such coal exist but are not now being mined.

The flaring or combustion of any refinery process gas stream or any other process gas stream that contains sulfur compounds measured as hydrogen sulfide can be limited to a concentration of 10 grains per 100 standard cubic feet (23 gm/100scm) of gas. This limitation on combustion of process gas relates to the control of sulfur oxide emissions that would result from burning untreated process gas from refinery operations or coke ovens containing hydrogen sulfide and other sulfur compounds. Hydrogen sulfide emissions can be controlled by requiring incineration or other equally effective means for all process units. Approximately 95 to 99 percent of the sulfur compounds must be removed from the process gas stream to meet this emission limitation. It may be appropriate to consider exemption of very small units which economically may not be able to achieve this level of control.

3.2 Sulfuric acid plants. The emissions of sulfur dioxide from sulfuric acid plants can be limited to 6.5 pounds per ton (3.26 kg./metric ton) of 100 percent acid produced. This emission limitation is equivalent to an overall so, to SO, conversion efficiency of 99.5 percent or a stack gas concentation of about 250 to 550 p.p.m. of sulfur dioxide, by volume, depending on the strength of the feed gas.

3.3 Sulfur recovery plants. The emission of sulfur oxides, calculated as sulfur dioxide, from a sulfur recovery plant can be limited to 0.01 pound (kg.) per pound (kg.) of sulfur processed. Approximately 99.5 percent of the sulfur processed must be recovered to meet this limitation. Existing plants typically recover 90 to 97 percent of the sulfur. This emission limitation corresponds to a sulfur dioxide concentration of about 1,300 p.p.m., by volume.

3.4 Nonferrous smelters. Technology is available to limit emission of sulfur oxides, calculated as sulfur dioxide, from primary nonferrous smelters according to the following equations:

Copper smelters: Y=0.2X.
Zinc smelters: Y=0.564X0.85.

Lead smelters: Y=0.98X0.77.
Where:

X=Total sulfur fed to smelter (lb./hr.).

Y=Sulfur Dioxide Emissions (1b./hr.). These emission limitations are equivalent to removal of about 90 percent of the input-sul

fur to the smelter for most copper smelters and somewhat higher for most lead and zinc smelters. Technology capable of achieving such emission limitations may not be applicable to all existing smelters. In such cases, iess restrictive control can be coupled with restricted operations to achieve air quality standards.

3.5 Sulfite pulp mills. The total sulfite pulp mill emissions of sulfur oxides, calculated as sulfur dioxide, from blow pits, washer vents, storage tanks, digester relief, and recovery system, can be reduced to 9 pounds per air-dried ton (4.5 kg./metric ton) of pulp produced. This emission limitation has applie cation only to those sulfite mills that install waste liquor recovery systems for water pollution control or other purposes. The installation of a recovery system can result in signifi. cant sulfur oxides emissions if not properly designed. For sulfite mills with existing recovery systems, & sulfur oxides emission limitation of 20 pounds per air-dried ton (9 kg./metric ton) of pulp may be more reasonable due to economic considerations. 4.0 CONTROL OF ORGANIC COMPOUNDS

EMISSIONS The following emission limitations are applicable to the principal stationary source of organic compound emissions. Reducing total organic compound emissions will reduce photochemical oxidant formation. Such control of organic compound emissions may appropriately be considered in areas where application of the Federal motor vehicle emission standards will not produce the emission reductions necessary for attainment and maintenance of the national ambient air quality standards for photochemical oxidants. These emission limitations emphasize reduction of total organic compound emissions, rather than substitution of "nonreactive" or "less reactive" organic compounds for those already in use, because there is evidence that very few organic compounds are photochemically nonreactive. Substitution may be useful, however, where it would result in a clearly evidunt decrease in reactiv. ity and thus tend to reduce photochemical oxidant formation. The extent to which application of these emission limitations would reduce photochemical oxidant formation in a given air quality control region will depend on the "mix" of emission sources in the region. These limitations are separable, 1.e., one or more portions can be considered, as necessary.

4.1 Storage of volatile organic compounds. The storage of volatile organic compounds in any stationary tank, reservoir or other container of more than 40,000 gallons (150,000 liters) can be in a pressure tank capable of maintaining working pressures sufficient at all times to prevent vapor or gas loss to the atmosphere. If this cannot be done, the tank can be equipped with a vapor loss control device such as:

(a) A floating roof, consisting of a pontoon type, double deck type roof or internal

floating cover, which will rest on the surface vapor loss control devices, properly installed of the liquid contents and be equipped with in good working order and in operation: a closure seal or seals to close the space be- (a) A container having all openings sealed tween the roof edge and tank wall. This con- and totally enclosing the liquid contents. All trol equipment may not be appropriate i gauging and sampling devices can be gasthe volatile organic compounds have a vapor tight except when gauging or sampling is pressure of 11 pounds per square Inch abso- taking place. lute (568 mm. Hg) or greater under actual (b) A container equipped with a floating storage conditions. All tank gauging or sam- roof, consisting of a pontoon type, doublo pling devices can be gas-tight except when deck type roof, or internal floating cover, tank gauging or sampling is taking place. which will rest on the surface of the con

(b) A vapor recovery system, consisting of tents and be equipped with a closure seal or a vapor gathering system capable of collect- seals to close the space between the roof edge ing the volatile organic compound vapors and container wall. All gauging and sampling and gases discharged, and a vapor disposal devices can be gas-tight except when gauging system capable of processing such volatile or sampling is taking place. organic vapors and gases so as to prevent (c) A container equipped with a vapor retheir emission to the atmosphere and all covery system consisting of a vapor gathering tank gauging and sampling devices can be system capable of collecting the organio gas-tight except when gauging or sampling vapors and gases discharged and a vapor disis taking place. These emission limitations posal system capable of processing such orare not intended for application to under- ganic vapors and gases so as to prevent their ground tanks used for long-term storago, emission to the atmosphere and with all conwhere filling operations occur frequently. tainer gauging and sampling devices gas

The storage of any volatile organic com- tight except when gauging or sampling to pound in any stationary storage vessel more taking place. This emission limitation will than 250-gallon (950 liter) capacity can be reduce organic compound emissions from unin a vessel equipped with a permanent sub- controlled waste water separator units apmerged all pipe or fitted with a vapor re- proximately 95 to 100 percent. covery system. This emission limitation will 4.4 Pumps and compressors. All pumpe reduce volatile organic emissions 90 to 100 and compressors handling volatile organic percent from uncontrolled sources of storage compounds can be equipped with mechaniin vessels 40,000 gallon capacity or greater cal seals or other equipment of equal and approximately 40 percent from uncon- efficiency. trolled sources of storage in vessels 250 gal- 4.5 Waste gas disposal. Any waste gas lon capacity or greater.

stream containing organic compounds from 4.2 Volatile organic compounds loading any ethylene producing plant or other othfacilities. The loading of volatile organic ylene emission source can be burned at compounds into any tank, truck, or trailer 1,300° F. (704. C.) for 0.3 second or greater having a capacity in excess of 200 gallons (760 in a direct-flame afterburner or an equally liters) con bo from & loading facility effective device. This does not apply to emerequipped with a vapor collection and disposal gency reliefs and vapor blowdown systems. system. Also, the loading facility can be The emission of organic compounds from a equipped with a loading arm with a vapor vapor blowdown system or emergency relief collection adaptor, pneumatic, hydraulic or can be burned by smokeless flares, or an other mechanical means to force a vapor- equally effective control device. This emistight seal between the adaptor and the hatch. sion limitation will reduce organic compound A means can be provided to prevent drainage emissions approximately 98 percent. of liquid organic compounds from the load- 4.6 Organic solvents. The emission of ing device when it is removed from the hatch organic compounds of more than 3 pounds of any tank, truck, or trailer, or to accom- (1.3 kg.) per hour or 15 pounds (6.8 kg.) per plish complete drainage before the removal. day from any equipment can be reduced by When loading is effected through means other at least 85 percent. This can be accomplished than batches, all loading and vapor lines by: can be equipped with fittings which make (a) Incineration, provided that 90 percent vapor-tight connections and which close or more of the carbon in the organic comautomatically when disconnected. This emis- pounds being incinerated is oxidized to carsion limitation will result in 55 to 60 percent bon dioxide, or reduction in volatile organic emissions from (b) Carbon adsorption. uncontrolled sources in gasoline marketing This limitation can be applied to a variety and other organic transfer operations.

of solvent users including industrial surface 4.3 Volatile organic compounds water coatings, dry cleaning, degreasing and printseparation. Single or multiple compartment ing operations. Surface coating operations volatile organic compounds water separators may appropriately be exempted from this which receive effluent water containing 200 limitation when the coating's solvent makegallons (760 liters) & day or more of any up is water-based and does not exceed 20 volatile organic compound from any equip- percent of organic compounds by volume. ment processing, refining, treating, storing or Organic solvents which have been shown to handling volatile organic compounds having be virtually unreactive in the formation of & Reid vapor pressure of 0.5 pound or greater oxidants, e.g., saturated halogenated hydrocan be equipped with one of the following carbons, perchlorethylene, benzene, acetone,

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equivalent to a nitrogen dioxide concentrs-
tion of 400 p.p.m., by volume.
(36 F.R. 23398, Nov. 25, 1971, as amended at
36 F.R. 25233, Dec. 30, 1971)
APPENDIX C-MAJOR POLLUTANT SOURCES

CHEMICAL PROCESS INDUSTRIES
Adipic acid.
Ammonia.
Ammonium nitrate.
Carbon black.
Charcoal.:
Chlorine.
Detergent and soap.1
Explosives (TNT and nitrocellulose).
Hydrofluoric acid.
Nitric acid.
Paint and varnish manufacturing.
Phosphoric acid.1
Phthalic anhydride.
Plastics manufacturing.'
Printing ink manufacturing.
Sodium carbonate.1
Sulfuric acid.1
Synthetic flbers.
Synthetic rubber.
Terephthalic acid.

FOOD AND AGRICULTURAL INDUSTRIES
Alfalfa dehydrating.'
Ammonium nitrate.
Coffee roasting?
Cotton ginning."
Feed and grain."
Fermentation processes.
Fertilizers.
Fish meal processing.
Meat smoke houses,
Starch manufacturing.
Sugar cane processing.

METALLURGICAL INDUSTRIES
Primary metals industries:

Aluminum ore reduction,
Copper Smelters.
Ferroalloy production."
Iron and steel mills.
Lead smelters.
Metallurgical coke manufacturing.'

Zinc.
Secondary metals industries:

Aluminum operations.
Brass and bronze smelting.
Ferroalloys."
Gray iron foundries.
Lead smelting.
Magnesium smelting.
Steel foundries.
Zinc processes.

5.0

and C.-C. n-paraffins also may be considered for exemption. Other compounds which have been shown to have low reactivity include cyclohexanone, ethyl acetate, diethylamine, isobutyl acetate, isopropyl alcohol, methyl benzoate, 2-nitropropane, phenyl acetate and triethylamine. This emission limitation may impose an economic burden upon some paint spray booth Installations. If such sources are not major contributors to hydrocarbon pollution levels, they may appropriately be considered for exemption.

4.7 Architectural coatings for buildings. The emission of organic compounds from architectural coatings can be reduced by requiring the use of water-base or other coatings having an organic solvent content of less than 20 percent by volume. The effectiveness of the limitations set forth in $$ 4.6 and 4.7 will vary, depending on the nature and amounts of emissions in an area; rough estimate based on Los Angeles emission data indicates that application of the limitation would result in a 70 percent reduction in organic solvent emissions. In estimating the effectiveness, it should be assumed that all organic emissions are reactive; use of exempt solvents as substitutes for regulated solvents may be considered 100 percent effective in reducing reactive organic solvent emissions.

CONTROL OF CARBON MONOXIDE EMISSIONS The emissions of carbon monoxide can be limited by requiring complete secondary combustion of waste gas generated in such operations as a grey iron cupola, blast furnace, basic oxygen steel furnace, catalyst regeneration of a petroleum cracking system, petroleum fuid coker or other petroleum process. 6.0 CONTROL OF NITROGEN OXIDES EMISSIONS

6.1 Fuel burning equipment. The emission of nitrogen oxides, calculated as nitrogen dioxide, from gas-fired fuel burning equipment can be limited to 0.2 pound per million B.t.u. (0.36 gm/100 gm-cal) of heat input. This emission limitation is about equivalent to a nitrogen dioxide concentration of 175 p.p.m., by volume, on a dry basis at 3 percent oxygen and represents about a 50 percent reduction in nitrogen oxide emissions from uncontrolled gas-fired equipment.

The emission of nitrogen oxides, calculated as nitrogen dioxide, from oil-fired fuel burning equipment can be limited to 0.30 pound per million B.t.u. (0.54 gm /100 gm-cal) of heat input. This emission limitation is about equivalent to a nitrogen dioxide concentration of 230 p.p.m., by volume, on a dry basis, at 3 percent oxygen and represents about a 50 percent reduction in nitrogen oxide emissions from uncontrolled oilfired fuel burning equipment.

6.2 Nitric acid manufacture. The emission of nitrogen oxides, calculated as nitrogen dioxide, from nitric acid manufacturing plants can be limited to 5.5 pounds per ton (2.8 kg. /metric ton) of 100 percent acid produced. This emission limitation is about

MINERAL PRODUCTS INDUSTRIES

Asphalt roofing.
Asphaltic concrete batching.1
Bricks and related clay refractories.
Calcium carbide.1
Castable refractories.
Cement.
Ceramic and clay processes.

(See footnote 1 on page 239.)

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