cause the low-pressure mercury lamp radiates at several wavelengths, the photometer must incorporate suitable means to assure that no O, is generated in the cell by the lamp, and that at least 99.5% of the radiation sensed by the detector is 254 nm radiation. (This can be readily achieved by prudent selection of optical filter and detector response characteristics.) The length of the light path through the absorption cell must be known with an accuracy of at least 99.5%. In addition, the cell and associated plumbing must be designed to minimize loss of O, from contact with cell walls and gas handling components. See Reference 9 for additional information.

3.2 Air flow controllers. Devices capable of regulating air flows as necessary to meet the output stability and photometer precision requirements.

3.3 Ozone generator. Device capable of generating stable levels of O, over the required concentration range.

3.4 Output manifold. The output manifold should be constructed of glass, Teflon, or other relatively inert material, and should be of sufficient diameter to insure a negligible pressure drop at the photometer connection and other output ports. The system must have a vent designed to insure atmospheric pressure in the manifold and to prevent ambient air from entering the manifold.

3.5 Two-way valve. Manual or automatic valve, or other means to switch the photometer flow between zero air and the O, concentration.

3.6 Temperature indicator. Accurate to ±1°C.

3.7 Barometer or pressure indicator. Accurate to ±2 torr.

4. Reagents.

4.1 Zero air. The zero air must be free of contaminants which would cause a detectable response from the O, analyzer, and it should be free of NO, C.H.. and other species which react with O1. A procedure for generating suitable zero air is given in Reference 9. As shown in Figure 1, the zero air supplied to the photometer cell for the I. reference measurement must be derived from the same source as the zero air used for generation of the ozone concentration to be assayed (I measurement). When using the photometer to certify a transfer standard having its own source of ozone, see Reference 8 for guidance on meeting this requirement.

5. Procedure.

5.1 General operation. The calibration photometer must be dedicated exclusively to use as a calibration standard. It should always be used with clean, filtered calibration gases, and never used for ambient a ir sampling. Consideration should be given to locating the calibration photometer in a clean laboratory where it can be stationary,

protected from physical shock, operated by a responsible analyst, and used as a common standard for all field calibrations via transfer standards.

5.2 Preparation. Proper operation of the photometer is of critical importance to the accuracy of this procedure. The following steps will help to verify proper operation. The steps are not necessarily required prior to each use of the photometer. Upon initial operation of the photometer, these steps should be carried out frequently, with all quantitative results or indications recorded in a chronological record either in tabular form or plotted on a graphical chart. As the performance and stability record of the photometer is established, the frequency of these steps may be reduced consistent with the documented stability of the photometer. 5.2.1 Instruction manual: Carry out all set up and adjustment procedures or checks as described in the operation or instruction manual associated with the photometer.

5.2.2 System check: Check the photometer system for integrity, leaks, cleanliness, proper flowrates, etc. Service or replace filters and zero air scrubbers or other consumable materials, as necessary.

5.2.3 Linearity: Verify that the photometer manufacturer has adequately established that the linearity error of the photometer is less than 3%, or test the linearity by dilution as follows: Generate and assay an O, concentration near the upper range limit of the system (0.5 or 1.0 ppm), then accurately dilute that concentration with zero air and reassay it. Repeat at several different dilution ratios. Compare the assay of the original concentration with the assay of the diluted concentration divided by the dilution ratio, as follows

standards, with calibration photometers used by other agencies or laboratories.

5.2.5 Ozone losses: Some portion of the O, may be lost upon contact with the photometer cell walls and gas handling components. The magnitude of this loss must be determined and used to correct the calculated O, concentration. This loss must not exceed 5%. Some guidelines for quantitatively determining this loss are discussed in Reference 9.

5.3 Assay of O, concentrations.

5.3.1 Allow the photometer system to warm up and stabilizer.

5.3.2 Verify that the flowrate through the photometer absorption cell, F allows the cell to be flushed in a reasonably short period of time (2 liter/min is a typical flow). The precision of the measurements is inversely related to the time required for flushing, since the photometer drift error increases with time.

5.3.3 Insure that the flowrate into the output manifold is at least 1 liter/min greater than the total flowrate required by the photometer and any other flow demand connected to the manifold.

5.3.4 Insure that the flowrate of zero air, F2, is at least 1 liter/min greater than the flowrate required by the photometer.

5.3.5 With zero air flowing in the output manifold, actuate the two-way valve to allow the photometer to sample first the manifold zero air, then F. The two photometer readings must be equal (I=I).

NOTE: In some commercially available photometers, the operation of the two-way valve and various other operations in section 5.3 may be carried out automatically by the photometer.

5.3.6 Adjust the O, generator to produce an O, concentration as needed.

5.3.7 Actuate the two-way valve to allow the photometer to sample zero air until the absorption cell is thoroughly flushed and record the stable measured value of I..

5.3.8 Actuate the two-way valve to allow the photometer to sample the ozone concentration until the absorption cell is thoroughly flushed and record the stable measured value of I.

5.3.9 Record the temperature and pressure of the sample in the photometer absorption cell. (See Reference 9 for guidance.)

5.3.10 Calculate the O, concentration from equation 4. An average of several determinations will provide better precision.

a = absorption coefficient of O, at 254 nm=308 atm cm at 0°C and 760 torr l=optical path length, cm T=sample temperature, K P sample pressure, torr

L= correction factor for O, losses from 5.2.5 (1-fraction O, lost).

NOTE: Some commercial photometers may automatically evaluate all or part of equation 4. It is the operator's responsibility to verify that all of the information required for equation 4 is obtained, either automatically by the photometer or manually. For "automatic" photometers which evaluate the first term of equation 4 based on a linear approximation, a manual correction may be required, particularly at higher O, levels. See the photometer instruction manual and Reference 9 for guidance.

5.3.11 Obtain additional O, concentration standards as necessary by repeating steps 5.3.6 to 5.3.10 or by Option 1.

5.4 Certification of transfer standards. A transfer standard is certified by relating the output of the transfer standard to one or more ozone standards as determined according to section 5.3. The exact procedure varies depending on the nature and design of the transfer standard. Consult Reference 8 for guidance.

5.5 Calibration of ozone analyzers. Ozone analyzers are calibrated as follows, using ozone standards obtained directly according to section 5.3 or by means of a certified transfer standard.

5.5.1 Allow sufficient time for the O, analyzer and the photometer or transfer standard to warmup and stabilize.

5.5.2 Allow the O, analyzer to sample zero air until a stable response is obtained and adjust the O, analyzer's zero control. Offsetting the analyzer's zero adjustment to +5% of scale is recommended to facilitate observing negative zero drift. Record the stable zero air response as "Z".

5.5.3 Generate an O1 concentration standard of approximately 80% of the desired upper range limit (URL) of the O, analyzer. Allow the O, analyzer to sample this O, concentration standard until a stable response is obtained.

5.5.4 Adjust the O, analyzer's span control to obtain a convenient recorder response as indicated below:

URL upper range limit of the O, analyzer, ppm

Z recorder response with zero air, % scale Record the O, concentration and the corresponding analyzer response. If substantial adjustment of the span control is necessary, recheck the zero and span adjustments by repeating steps 5.5.2 to 5.5.4.

5.5.5 Generate several other O, concentration standards (at least 5 others are recommended) over the scale range of the O, analyzer by adjusting the O, source or by Option 1. For each O, concentration standard, record the O, and the corresponding analyzer response.

5.5.6 Plot the O, analyzer responses versus the corresponding O, concentrations and draw the O, analyzer's calibration curve or calculate the appropriate response factor.

5.5.7 Option 1: The various O, concentrations required in steps 5.3.11 and 5.5.5 may be obtained by dilution of the O, concentration generated in steps 5.3.6 and 5.5.3. With this option, accurate flow measurements are required. The dynamic calibration system may be modified as shown in Figure 2 to allow for dilution air to be metered in downstream of the O, generator. A mixing chamber between the O, generator and the output manifold is also required. The flowrate through the O, generator (F.) and the dilution air flowrate (F) are measured with a reliable flow or volume standard traceable to NBS. Each O, concentration generated by dilution is calculated from:

1. E.C.Y. Inn and Y. Tanaka, "Absorption coefficient of Ozone in the Ultraviolet and Visible Regions", J. Opt. Soc. Am., 43, 870 (1953).

2. A. G. Hearn, "Absorption of Ozone in the Ultraviolet and Visible Regions of the Spectrum", Proc. Phys. Soc. (London), 78, 932 (1961).

3. W. B. DeMore and O. Raper, "Hartley Band Extinction Coefficients of Ozone in the Gas Phase and in Liquid Nitrogen, Carbon Monoxide, and Argon", J. Phys. Chem., 68, 412 (1964).

4. M. Griggs, "Absorption Coefficients of Ozone in the Ultraviolet and Visible Regions", J. Chem. Phys., 49, 857 (1968).

5. K. H. Becker, U. Schurath, and H. Seitz, "Ozone Olefin Reactions in the Gas Phase. 1. Rate Constants and Activation Energies", Int'l Jour. of Chem. Kinetics, VI, 725 (1974).

6. M. A. A. Clyne and J. A. Coxom, "Kinetic Studies of Oxy-halogen Radical Systems", Proc. Roy. Soc., A303, 207 (1968).

7. J. W. Simons, R. J. Paur, H. A. Webster, and E. J. Bair, "Ozone Ultraviolet Photolysis. VI. The Ultraviolet Spectrum", J. Chem. Phys., 59, 1203 (1973).

8. "Transfer Standards for Calibration of Ambient Air Monitoring Analyzers for Ozone", EPA Publication available from EPA, Department E (MD-77), Research Triangle Park, N.C. 27711.

9. "Technical Assistance Document for the Calibration of Ambient Ozone Monitors", EPA Publication available from EPA, Department E (MD-77), Research Triangle Park, N.C. 27711.

where:

Temporary Alternative Calibration procedure-(Boric Acid-Potassium Iodide). This procedure may be used as an alternative to the Ultraviolet Photometry procedure for direct calibration of ozone analyzers-but not to certify transfer standards-until [18 months after the date of final promulgation]. After that time this procedure can be used only as a transfer standard in accordance with the guidance and specifications set forth in Reference 4, "Transfer Standards for Calibration of Ambient Air Monitoring Analyzers for Ozone".

1. Principle. This calibration procedure (1) is based upon the reaction between ozone (O1) and potassium iodide (KI) to release iodine (I2) according to the stoichiometric equation: (2)

O3+21+ 2H * → I2+ H2O + O2

(1)

The stoichiometry is such that the amount of I, released is equivalent to the amount of O.. absorbed. Ozone is absorbed in a 0.1M boric acid (HBO) solution containing 1% KI, and the I, released reacts with excess iodide ion (I) to form triiodide ion (I ̄) which is measured spectrophotometrically at a wavelength of 352 nm. The output of a

stable O, generator is assayed in this manner, and the generator is immediately used to calibrate the O, analyzer. The O, generator must be used immediately after calibration and without physical movement, and it is recalibrated prior to each use. Alternatively, the O, analyzer may be calibrated by assaying the O, concentrations using the prescribed procedure while simultaneously measuring the corresponding O, analyzer responses. Ozone concentration standards may also be generated by an optional dilution technique. With this option, the highest O, concentration standard is assayed using the prescribed procedure. The additional O, concentration standards required are then obtained by dilution.

2. Apparatus. Figures 1 and 2 illustrate a typical BAKI O, calibration system and show the suggested configuration of the components listed below. All connections between components downstream of the O, generator should be of glass, Teflon or other relatively inert material.

2.1 Air flow controller. Device capable of maintaining a constant air flowrate through the O, generator within ±2%.

2.2 Air flowmeter. Calibrated flowmeter capable of measuring and monitoring the